Processing, Structure, and Properties of PAN/MWNT Composite Fibers
- Categori
- 2006~2010
- Journal
- Macromolecular Materials and Engineering
- Year
- 2010
- Page
- 742-749
Conventional dry-jet wet fiber spinning techniques were used to fabricate continuous PAN/MWNT composite fibers with up to 20 wt.-% nanotube loading. PAN at the MWNT interface exhibited lower solubility under thermodynamically favorable conditions than in bulk PAN, indicating good interfacial interaction. Due to the PAN/MWNT interaction at the interface, thermal shrinkage decreases with increasing MWNT loading (5 to 20 wt.-%). For high MWNT loadings, PAN/MWNT composite fiber at 15 wt.-% MWNT loading showed an axial electrical conductivity of 1.24 S · m−1. For all loadings, PAN/MWNT composite fibers exhibited higher tensile moduli than theoretically predicted by rule-of-mixture calculations, suggesting good reinforcement of the PAN by MWNT.
